| School Name | Grades | Address | Zip | Phone | County | Type | District Name |
| Benton Heights Elementary School of the Arts | PK-5 | 1200 Concord Ave
Monroe, NC | 28110 | (704) 296-3100 | Union | public | Union County Public Schools |
| Central Academy of Technology & Arts | 9-12 | 600 Brewer Dr
Monroe, NC | 28112 | (704) 296-3088 | Union | public | Union County Public Schools |
| East Elementary School | PK-5 | 515 Elizabeth Ave
Monroe, NC | 28112 | (704) 296-3110 | Union | public | Union County Public Schools |
| Fairview Elementary School | K-5 | 110 Clontz Road
Monroe, NC | 28110 | (704) 753-2800 | Union | public | Union County Public Schools |
| First Assembly Christian School | PK-12 | 2500 Arnold Dr
Monroe, NC | 28110 | (704) 283-2739 | Union | private | |
| Monroe Christian Academy | PK-12 | 1721 N Charlotte Ave
Monroe, NC | 28110 | (704) 289-4911 | Union | private | |
| Monroe High School | 9-12 | 1 High School Dr
Monroe, NC | 28112 | (704) 296-3130 | Union | public | Union County Public Schools |
| Monroe Middle School | 6-7 | 601 E Sunset Drive
Monroe, NC | 28112 | (704) 296-3120 | Union | public | Union County Public Schools |
| Parkwood High School | 9-12 | 3220 Parkwood School Rd
Monroe, NC | 28112 | (704) 764-2900 | Union | public | Union County Public Schools |
| Parkwood Middle School | 6-7 | 3219 Parkwood School Rd
Monroe, NC | 28112 | (704) 764-2910 | Union | public | Union County Public Schools |
| Piedmont High School | 9-12 | 3006 Sikes Mill Road
Monroe, NC | 28110 | (704) 753-2810 | Union | public | Union County Public Schools |
| Piedmont Middle School | 6-7 | 2816 Sikes Mill Rd
Monroe, NC | 28110 | (704) 753-2840 | Union | public | Union County Public Schools |
| Positive Impact of Union County | n/a | 600 E Franklin St
Monroe, NC | 28112 | (704) 283-0370 | Union | private | |
| Price Academy and Learning Center | K-5 | 1203 Concord Ave.
Monroe, NC | 28110 | (704) 226-1714 | Union | private | |
| Prospect Elementary School | K-5 | 3005 Ruben Rd
Monroe, NC | 28112 | (704) 764-2920 | Union | public | Union County Public Schools |
| Rock Rest Elementary School | PK-5 | 814 Old Pageland-Monroe Rd
Monroe, NC | 28112 | (704) 290-1513 | Union | public | Union County Public Schools |
| Rocky River Elementary School | PK-5 | 500 N. Rocky River Road
Monroe, NC | 28110 | (704) 290-1523 | Union | public | Union County Public Schools |
| Sardis Elementary School | PK-5 | 4416 Sardis Church Road
Monroe, NC | 28110 | (704) 882-4303 | Union | public | Union County Public Schools |
| Shiloh Elementary School | K-5 | 5210 Rogers Rd
Monroe, NC | 28110 | (704) 296-3035 | Union | public | Union County Public Schools |
| Shining Light Baptist Academy | PK-12 | 2541 Old Charlotte Hwy
Monroe, NC | 28110 | (704) 283-1480 | Union | private | |
| Sun Valley Elementary School | K-5 | 5200 Rogers Rd
Monroe, NC | 28110 | (704) 290-1559 | Union | public | Union County Public Schools |
| Sun Valley High School | 9-12 | 5211 Old Charlotte Hwy
Monroe, NC | 28110 | (704) 296-3020 | Union | public | Union County Public Schools |
| Sunset Park Christian School | K-12 | 1320 South Hayne Street
Monroe, NC | 28112 | (704) 283-2414 | Union | private | |
| Tabernacle Christian School | PK-12 | 2900 Walkup Ave
Monroe, NC | 28110 | (704) 283-4395 | Union | private | |
| Union Academy Charter School | K-12 | 675 North M.L. King Jr. Blvd.
Monroe, NC | 28110 | (704) 238-8883 | Union | charter | Union Academy |
| Union County Early College | 9-12 | 4209a Old Charlotte Hwy
Monroe, NC | 28110 | (704) 290-1565 | Union | public | Union County Public Schools |
| Unionville Elementary School | K-5 | 4511 Unionville Rd
Monroe, NC | 28110 | (704) 296-3055 | Union | public | Union County Public Schools |
| Walter Bickett Elementary School | PK-5 | 830 South Ml King Blvd
Monroe, NC | 28112 | (704) 283-8520 | Union | public | Union County Public Schools |
| Wesley Chapel Elementary School | K-5 | 110 Potter Rd S
Monroe, NC | 28110 | (704) 296-3081 | Union | public | Union County Public Schools |
| Wolfe School | n/a | 722 Brewer Drive
Monroe, NC | 28112 | (704) 290-1568 | Union | public | Union County Public Schools |
