| School Name | Grades | Address | Zip | Phone | County | Type | District Name |
| Columbia Elementary School | K-5 | 150 Columbus Rd
Mount Vernon, OH | 43050 | (740) 393-5975 | Knox | public | Mount Vernon City School District |
| Dan Emmett Elementary School | K-5 | 108 Mansfield Ave
Mount Vernon, OH | 43050 | (740) 393-5950 | Knox | public | Mount Vernon City School District |
| East Elementary School | K-5 | 714 E Vine St
Mount Vernon, OH | 43050 | (740) 393-5985 | Knox | public | Mount Vernon City School District |
| Mount Vernon Academy | 9-12 | P.O. Box 311
Mount Vernon, OH | 43050 | (740) 397-5411 | Knox | private | |
| Mount Vernon High School | 9-12 | 300 Martinsburg Rd
Mount Vernon, OH | 43050 | (740) 393-5900 | Knox | public | Mount Vernon City School District |
| Mount Vernon Middle School | 6-8 | 298 Martinsburg Rd
Mount Vernon, OH | 43050 | (740) 392-6867 | Knox | public | Mount Vernon City School District |
| Mount Vernon SDA Elementary School | PK-8 | P.O. Box 891
Mount Vernon, OH | 43050 | (740) 393-7060 | Knox | private | |
| Pleasant Street Elementary School | PK-5 | 305 E Pleasant St
Mount Vernon, OH | 43050 | (740) 393-5990 | Knox | public | Mount Vernon City School District |
| St. Vincent De Paul School | PK-8 | 206 E Chestnut St
Mount Vernon, OH | 43050 | (740) 393-3611 | Knox | private | |
| Twin Oak Elementary School | K-5 | 8888 Martinsburg Rd
Mount Vernon, OH | 43050 | (740) 393-5970 | Knox | public | Mount Vernon City School District |
