| | Libertyville, IL | Lake Zurich, IL | United States |
| Population | 20,616 | 19,807 | 329,725,481 |
| Female Population | 52.7% | 50.8% | 50.5% |
| Male Population | 47.3% | 49.2% | 49.5% |
| Median Age | 42.1 | 40.8 | 38.4 |
| space3 | | | |
| Population - 2010 | 20,420 | 19,719 | 309,327,143 |
| Population - 2000 | 20,742 | 18,104 | 285,036,114 |
| Population - 1990 | 19,174 | 14,947 | 251,960,433 |
| Pop. 2000 to Now | -2.8% | 9.2% | 15.6% |
| Pop. 1990 to Now | 5.1% | 32.2% | 30.8% |
| space4 | | | |
| Population Density | 2,340.6 | 2,898.3 | 93.4 |
| Land Area | 8.8 | 6.8 | 3,531,905.4 |
| Water Area | 0.4 | 0.4 | 264,836.8 |
| space | | | |
| Est. Total Population By Age | | | |
| | Libertyville, IL | Lake Zurich, IL | United States |
| Age 0 to 4 | 5.6% | 5.6% | 5.9% |
| Age 5 to 9 | 6.9% | 6.5% | 6.1% |
| Age 10 to 14 | 8.5% | 6.7% | 6.6% |
| Age 15 to 17 | 5.1% | 4.0% | 3.9% |
| Age 18 to 20 | 3.9% | 3.2% | 4.0% |
| Age 21 to 24 | 3.0% | 5.9% | 5.2% |
| Age 25 to 34 | 8.3% | 11.0% | 13.8% |
| Age 35 to 44 | 11.8% | 12.5% | 12.9% |
| Age 45 to 54 | 17.1% | 15.6% | 12.6% |
| Age 55 to 59 | 7.5% | 8.7% | 6.7% |
| Age 60 to 64 | 5.7% | 7.6% | 6.3% |
| Age 65 to 74 | 8.6% | 8.3% | 9.6% |
| Age 75 to 84 | 5.6% | 3.0% | 4.5% |
| Age 85 and over | 2.5% | 1.4% | 1.9% |
| space1 | | | |
| Race | | | |
| | Libertyville, IL | Lake Zurich, IL | United States |
| White | 83.5% | 84.5% | 59.4% |
| Black | 1.0% | 0.5% | 12.2% |
| Asian | 6.5% | 8.3% | 5.6% |
| Native American | 0.3% | 0.0% | 0.6% |
| Hawaiian, Pacific Islander | 0.0% | 0.0% | 0.2% |
| Other | 0.1% | 0.0% | 0.4% |
| Two or More Races | 2.2% | 2.8% | 3.2% |
| Hispanic | 6.5% | 3.9% | 18.4% |
| space2 | | | |
| Marriage & Family | | | |
| | Libertyville, IL | Lake Zurich, IL | United States |
| Married Population | 62.6% | 62.5% | 49.8% |
| Currently Married | 61.8% | 61.8% | 48.0% |
| Married but Separated | 0.8% | 0.8% | 1.8% |
| Single Population | 37.4% | 37.5% | 50.2% |
| Never Married | 25.3% | 26.3% | 33.8% |
| Divorced | 6.4% | 7.6% | 10.8% |
| Widowed | 5.7% | 3.6% | 5.6% |
| space5 | | | |
| Household Size | 2.70 | 2.76 | 2.60 |
| Households | 7,458 | 7,105 | 124,010,992 |
| Family Households | 5,499 | 5,673 | 80,755,759 |
| Married couple, w/children | 42.9% | 36.9% | 30.5% |
| Married couple, no children | 46.2% | 48.0% | 42.9% |
| Non Family Households | 1,959 | 1,432 | 43,255,233 |
| Single householder, w/children | 6.3% | 7.4% | 15.8% |
| Single householder, no children | 4.6% | 7.8% | 10.8% |